Comparison Study of Natural Dye Sensitisers in Dye-Sensitised Solar Cells

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Faisal Abdullah Sadeq
Cheikh Zakaria Eldjilali
Pei Ling Low
Gregory Soon How Thein
Kar Ban Tan
H. C. Ananda Murthy
Muhammad Aqeel Ashraf
Kah Yoong Chan

Abstract

This work explored the performance and characterisation of dye-sensitised solar cells (DSSCs) based on sustainable dyes, as compared to traditionally applied dyes consisting of metal compounds. Several natural sources were used to extract the dye, including mangosteen, thyme, coriander, spearmint, ginger, and papaya. The samples were investigated, and a comparison was made between the performance of each dye. The ruthenium sensitised control sample yielded a Power Conversion Efficiency (PCE) of 3.9642% with a Fill Factor (FF) of 69.434%. Among natural dye sensitisers anthocyanin pigment-rich dye from mangosteen performed the best with PCE and FF of 0.7677% and 68.55%, respectively. Other natural dye-sensitised samples all depicted PCE < 0.3% but relatively close FF, ranging from 50% to around 70%.

Article Details

How to Cite
[1]
F. A. Sadeq, “Comparison Study of Natural Dye Sensitisers in Dye-Sensitised Solar Cells”, Journal of Engineering Technology and Applied Physics, vol. 7, no. 2, pp. 26–34, Sep. 2025.
Section
Regular Paper for Journal of Engineering Technology and Applied Physics

References

“CO2 Emissions in 2022 – Analysis - IEA.”, [Available online on 29 March 2025] https://www.iea.org/reports/co2-emissions-in-2022.

S. Safieddine et al., “Antarctic Ozone Enhancement During the 2019 Sudden Stratospheric Warming Event,” Geophys. Res. Let.t, vol. 47, no. 14, pp. e2020GL0878102020.

I. Wohltmann et al., “Near-Complete Local Reduction of Arctic Stratospheric Ozone by Severe Chemical Loss in Spring 2020,” Geophys. Res. Lett., vol. 47, no. 20, pp. e2020GL089547, 2020.

“What is the current state of the ozone layer? — European Environment Agency,” [Available online on 29 March 2025] https://www.eea.europa.eu/themes/climate/ozone-depleting-substances-and-climate-change-1/protecting-the-ozone-layer-while.

“Monthly Climate Reports | Global Climate Report | Annual 2024 | National Centers for Environmental Information (NCEI),”

[Available online on 29 March 2025] https://www.ncei.noaa.gov/access/monitoring/monthly-report/global/202413.

S. C. Lim, M. M. F. Dawoud, Y. H. Kwok and W. Y. Wong, “Recent Progress in Floating Solar Photovoltaic Systems: A Review from Malaysia’s Perspective,” J. Eng. Technol. and Appl. Phys., vol. 6, no. 1, pp. 1–5, 2024.

S. M. Sultan and M. N. Ervina Efzan, “Review on Recent Photovoltaic/Thermal (PV/T) Technology Advances and Applications,” Solar Ener., vol. 173, pp. 939-954, 2018.

M. Benghanem et al., “Evaluation of the Performance of Polycrystalline and Monocrystalline PV Technologies in a Hot and Arid Region: An Experimental Analysis,” Sustainability, vol. 15, no. 20, pp. 14831, 2023.

F. Mohamed Rosly, G. L. Ong, T. S. Ong, C. H. Nee, S. A. Ibrahim and S. S. Yap, “Simulation and Fabrication of P3HT:PCBM Solar Cell,” J. Eng. Technol. and Appl. Phys., vol. 5, no. 2, pp. 5–8, 2023.

R. Wan et al., “Investigation on Thermally Evaporated Aluminium Contact Layers for Perovskite Solar Cell Applications,” Int. J. Integr. Eng., vol. 16, no. 3, pp. 28–35, 2024.

H. A. Fetouh, A. E. Dissouky, H. A. Salem, M. Fathy, B. Anis and A. E. Hady Kashyout, “Synthesis, Characterization and Evaluation of New Alternative Ruthenium Complex for Dye Sensitized Solar Cells,” Sci. Rep. 2024, vol. 14, no. 1, pp. 1–13, 2024.

S. Maw, “Performances Analysis and Comparison of Active and Hybrid Harmonic Filter in Photovoltaic Water Pumping System,” J. Eng. Technol. and Appl. Phys., vol. 5, no. 2, pp. 58–63, 2023.

I. Yahaya and A. N. Rosli, “A Flash Flood Warning System Using Solar Powered Node MCU,” J. Eng. Technol. and Appl. Phys., vol. 7, no. 1, pp. 45–49, 2025.

M. Grätzel, “Highly Efficient Nanocrystalline Photovoltaic Devices,” Platin. Met. Rev., vol. 38, no. 4, pp. 151 – 159, 1994.

M. A. M. Al-Alwani, A. B. Mohamad, N. A. Ludin, A. A. H. Kadhum and K. Sopian, “Dye-Sensitised Solar Cells: Development, Structure, Operation Principles, Electron Kinetics, Characterisation, Synthesis Materials and Natural Photosensitisers,” Renew. and Sustain. Ener. Rev., vol. 65, pp. 183-213, 2016.

C. Z. Eldjilali et al., “Electrochromic Performances of Tio2 Nanocrystals Thin Films for Smart Glass Applications,” Thin Solid Films, vol. 815, pp. 140636, 2025.

A. Aslam et al., “Dye-Sensitized Solar Cells (DSSCs) as A Potential Photovoltaic Technology for The Self-Powered Internet of Things (IoTs) Applications,” Solar Ener., vol. 207, pp. 874-892, 2020.

A. Roy, A. Ghosh, S. Bhandari, P. Selvaraj, S. Sundaram and T. K. Mallick, “Color Comfort Evaluation of Dye-Sensitized Solar Cell (DSSC) Based Building-Integrated Photovoltaic (BIPV) Glazing after 2 Years of Ambient Exposure,” J. Phys. Chem. C, vol. 123, no. 39, pp. 23834–23837, 2019.

M. Szindler, M. Szindler, A. Drygala, K. Lukaszkowicz, P. Kaim and R. Pietruszka, “Dye-Sensitized Solar Cell for Building-Integrated Photovoltaic (BIPV) Applications,” Materials, vol. 14, no. 13, pp. 3743, 2021.

N. I. M. Nawawi, G. Ijod, F. Abas, N. S. Ramli, N. Mohd Adzahan and E. Mohamad Azman, “Influence of Different Drying Methods on Anthocyanins Composition and Antioxidant Activities of Mangosteen (Garcinia mangostana L.) Pericarps and LC-MS Analysis of the Active Extract,” Foods, vol. 12, no. 12, pp. 2351, 2023.

S. Roseline, A. Yadav, B. Monteiro and F. S. Josephine, “Analysing The Various Pigments Present in Coloured Leaves”, DOI: 10.13140/RG.2.2.15304.33287.

A. Ali, P. Santoro, J. Mori, A. Ferrante and G. Cocetta, “Effect Of UV-B Elicitation on Spearmint’s (Mentha spicata L.) Morpho-Physiological Traits and Secondary Metabolites Production,” Plant. Growth Regul., vol. 104, no. 1, pp. 63–76, 2023.

J. M. El-Qudah, “Contents of Chlorophyll and Carotenoid Pigments In Common Thyme (Thymus vulgaris L.),” World Appl. Sci. J., vol. 29, no. 10, pp. 1277–1281, 2014.

Y. Iijima and A. Joh, “Pigment Composition Responsible for the Pale Yellow Color of Ginger (Zingiber officinale) Rhizomes,” Food Sci. Technol. Res., vol. 20, no. 5, pp. 971–978, 2014.

Y. H. Shen et al., “Exploring the Differential Mechanisms of Carotenoid Biosynthesis in The Yellow Peel and Red Flesh of Papaya,” BMC Genomics, vol. 20, pp. 40, 2019.

“Solaronix - Ruthenizer, Ruthenium Photo-Sensitizers,” [Available online on 29 March 2025] https://www.solaronix.com/materials/products/ruthenizer/.

M. E. Yeoh and K. Y. Chan, “Synthesis of Dye-sensitised Solar Cells Utilising Platinised Counter Electrode,” Mater. Res. Innov., vol. 21, no. 4, pp. 244–248, 2017.

M. E. Yeoh, K. Y. Chan and H. Y. Wong, “Investigation on The Thickness Effect of TiO2 Photo-Anode on Dye-Sensitized Solar Cell Performance,” Solid State Phenomena, vol. 280, pp. 76–80, 2018.

Z. Yu, N. Vlachopoulos, M. Gorlov and L. Kloo, “Liquid Electrolytes for Dye-Sensitized Solar Cells,” Dalton Trans., vol. 40, no. 40, pp. 10289–10303, 2011.

N. H. Astuti, N. A. Wibowo and M. R. S. S. N. Ayub, “The Porosity Calculation of Various Types of Paper Using Image Analysis,” Jurnal Pendidikan Fisika Indonesia, vol. 14, no. 1, pp. 46–51, 2018.

W. Li, R. Liang, A. Hu, Z. Huang and Y. N. Zhou, “Generation of Oxygen Vacancies in Visible Light Activated One-Dimensional Iodine TiO2 Photocatalysts,” RSC Adv., vol. 4, no. 70, pp. 36959–36966, 2014.

M. E. Yeoh et al., “A Novel Simplified Approach in Fabricating TiO2 Photoanodes for Dye-Sensitized Solar Cells,” Mater. Lett., vol. 349, pp. 134730, 2023.

L. Sun, “Asphalt Mix Homogeneity,” Structural Behavior of Asphalt Pavements, Elsevier Inc., pp. 821–921, 2016.

M. Ryan, “Progress in Ruthenium Complexes for Dye Sensitised Solar Cells,” Platin. Met. Rev., vol. 53, no. 4, pp. 216 – 218, 2009.

N. Sofyan, A. Ridhova, A. H. Yuwono and A. Udhiarto, “Fabrication of Solar Cells with TiO2 Nanoparticles Sensitized using Natural Dye Extracted from Mangosteen Pericarps,” Int. J. Technol., vol. 8, no. 7, pp. 1229-1238, 2017.

G. Calogero, J. H. Yum, A. Sinopoli, G. Di Marco, M. Grätzel and M. K. Nazeeruddin, “Anthocyanins and Betalains As Light-Harvesting Pigments for Dye-Sensitized Solar Cells,” Solar Ener., vol. 86, no. 5, pp. 1563-1575, 2012.

A. Sikder et al., “Characterization and Comparison of DSSCs Fabricated with Black Natural Dyes Extracted from Jamun, Black Plum, and Blackberry,” Energies, vol. 16, no. 20, pp. 7187, 2023.

W. Ghann et al., “Fabrication, Optimization and Characterization of Natural Dye Sensitized Solar Cell,” Sci. Rep., vol. 7, pp. 41470, 2017.

W. A. Ayalew and D. W. Ayele, “Dye-Sensitized Solar Cells Using Natural Dye as Light-Harvesting Materials Extracted from Acanthus Sennii Chiovenda Flower and Euphorbia Cotinifolia Leaf,” J. Sci.: Adv. Mater. and Device., vol. 1, no. 4, pp. 488-494, 2016.

E. M. Abdou, H. S. Hafez, E. Bakir and M. S. A. Abdel-Mottaleb, “Photostability of Low Cost Dye-sensitized Solar Cells Based on Natural and Synthetic Dyes,” Spectrochim. Acta A Mol. Biomol. Spectrosc., vol. 115, pp. 202–207, 2013.

S. Sarker, A. J. S. Ahammad, H. W. Seo and D. M. Kim, “Electrochemical Impedance Spectra of Dye-Sensitized Solar Cells: Fundamentals and Spreadsheet Calculation,” Int. J. Photoenergy, vol. 2014, no. 1, pp. 851705, 2014.

A. M. Ammar, H. S. H. Mohamed, M. M. K. Yousef, G. M. Abdel-Hafez, A. S. Hassanien and A. S. G. Khalil, “Dye-Sensitized Solar Cells (DSSCs) Based on Extracted Natural Dyes,” J. Nanomater, vol. 2019, no. 1, pp. 1867271, 2019.

A. Omar, M. S. Ali and N. Abd Rahim, “Electron Transport Properties Analysis of Titanium Dioxide Dye-Sensitized Solar Cells (TiO2-DSSCs) based Natural Dyes Using Electrochemical Impedance Spectroscopy Concept: A Review,” Solar Ener., vol. 207, pp. 1088-1121, 2020.